Site selectivity of alkali metal ions in KxRb3-xC60

Ichiro Hirosawa; Jun'ichiro Mizuki; Katsumi Tanigaki; Hidekazu Kimura

doi:10.1016/0038-1098(94)90417-0

Site selectivity of alkali metal ions in K_xRb_3-xC₆₀

Ichiro Hirosawa, Jun'ichiro Mizuki, Katsumi Tanigaki, Hidekazu Kimura

研究成果: Article › 査読

8 被引用数 (Scopus)

抄録

We observed crystal structures of K_xRb_3-xC₆₀ by X-ray diffraction, and found that Rb ions preferentially occupied octahedral interstitial sites. In the case of K₂RbC₆₀, Rb and K ions are accommodated in octahedral and tetrahedral sites respectively. As for the case of KRb₂C₆₀, Rb and K ions in tetrahedral interstitial sites were found to be in a random fashion by anomalous X-ray diffraction.

本文言語	English
ページ（範囲）	55-58
ページ数	4
ジャーナル	Solid State Communications
巻	89
号	1
DOI	https://doi.org/10.1016/0038-1098(94)90417-0
出版ステータス	Published - 1994 1月
外部発表	はい

ASJC Scopus subject areas

化学 (全般)
凝縮系物理学
材料化学

文献へのアクセス

10.1016/0038-1098(94)90417-0

他のファイルとリンク

引用スタイル

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title = "Site selectivity of alkali metal ions in KxRb3-xC60",

abstract = "We observed crystal structures of KxRb3-xC60 by X-ray diffraction, and found that Rb ions preferentially occupied octahedral interstitial sites. In the case of K2RbC60, Rb and K ions are accommodated in octahedral and tetrahedral sites respectively. As for the case of KRb2C60, Rb and K ions in tetrahedral interstitial sites were found to be in a random fashion by anomalous X-ray diffraction.",

author = "Ichiro Hirosawa and Jun'ichiro Mizuki and Katsumi Tanigaki and Hidekazu Kimura",

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AB - We observed crystal structures of KxRb3-xC60 by X-ray diffraction, and found that Rb ions preferentially occupied octahedral interstitial sites. In the case of K2RbC60, Rb and K ions are accommodated in octahedral and tetrahedral sites respectively. As for the case of KRb2C60, Rb and K ions in tetrahedral interstitial sites were found to be in a random fashion by anomalous X-ray diffraction.

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