Simple and efficient preparation of sterically protected 1,4-diphosphafulvenes

Akitake Nakamura, Kozo Toyota, Masaaki Yoshifuji

研究成果: Article

12 被引用数 (Scopus)

抄録

A new synthetic method for sterically protected 1,4-diphosphafulvenes (2-methylene-2,3-dihydro-1H-[1,3]diphospholes) has been developed starting from (arylethynyl)phosphines and ca. 0.25 molar amount of butyllithium. The catalytic mechanism of the reaction is discussed based on the results of deuterium-labelling experiments.

本文言語English
ページ(範囲)5223-5228
ページ数6
ジャーナルTetrahedron
61
22
DOI
出版ステータスPublished - 2005 5 30

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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