Sigmatropic and haptotropic rearrangements in organometallic chemistry

Ilya D. Gridnev

doi:10.1016/j.ccr.2007.10.021

Sigmatropic and haptotropic rearrangements in organometallic chemistry

Ilya D. Gridnev

研究成果: Review article › 査読

54 被引用数 (Scopus)

抄録

This review describes two kinds of fluxionality in organometallic compounds: rearrangements proceeding via breaking and reformation of either σ-(sigmatropic rearrangements) or π-bonds (haptotropic rearrangements).

本文言語	English
ページ（範囲）	1798-1818
ページ数	21
ジャーナル	Coordination Chemistry Reviews
巻	252
号	15-17
DOI	https://doi.org/10.1016/j.ccr.2007.10.021
出版ステータス	Published - 2008 8
外部発表	はい

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

文献へのアクセス

10.1016/j.ccr.2007.10.021

フィンガープリント「Sigmatropic and haptotropic rearrangements in organometallic chemistry」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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title = "Sigmatropic and haptotropic rearrangements in organometallic chemistry",

abstract = "This review describes two kinds of fluxionality in organometallic compounds: rearrangements proceeding via breaking and reformation of either σ-(sigmatropic rearrangements) or π-bonds (haptotropic rearrangements).",

keywords = "Dynamic NMR, Fluxionality, Haptotropic rearrangements, Organometallic complexes, Sigmatropic rearrangements, Sigmatropic shifts",

author = "Gridnev, {Ilya D.}",

note = "Funding Information: This work was financially supported by the Global COE Program of Tokyo Institute of Technology. ",

year = "2008",

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AU - Gridnev, Ilya D.

N1 - Funding Information: This work was financially supported by the Global COE Program of Tokyo Institute of Technology.

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N2 - This review describes two kinds of fluxionality in organometallic compounds: rearrangements proceeding via breaking and reformation of either σ-(sigmatropic rearrangements) or π-bonds (haptotropic rearrangements).

AB - This review describes two kinds of fluxionality in organometallic compounds: rearrangements proceeding via breaking and reformation of either σ-(sigmatropic rearrangements) or π-bonds (haptotropic rearrangements).

KW - Dynamic NMR

KW - Fluxionality

KW - Haptotropic rearrangements

KW - Organometallic complexes

KW - Sigmatropic rearrangements

KW - Sigmatropic shifts

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