Separation and recovery of Cm from Cm-Pu mixed oxide samples containing Am impurity

Hirokazu Hayashi, Hiromichi Hagiya, Seong Yun Kim, Yasuji Morita, Mitsuo Akabori, Kazuo Minato

研究成果: Article査読

4 被引用数 (Scopus)


Curium was separated and recovered as an oxalate from a Cm-Pu mixed oxide which had been a 244Cm oxide sample prepared more than 40 years ago and the ratio of 244Cm to 240Pu was estimated to 0.2:0.8. Radiochemical analyses of the solution prepared by dissolving the Cm-Pu mixed oxide in nitric acid revealed that the oxide contained about 1 at% of 243Am impurity. To obtain high purity curium solution, plutonium and americium were removed from the solution by an anion exchange method and by chromatographic separation using tertiary pyridine resin embedded in silica beads with nitric acid/methanol mixed solution, respectively. Curium oxalate, a precursor compound of curium oxide, was prepared from the purified curium solution. 11.9 mg of Cm oxalate having some amounts of impurities, which are 243Am (5.4 at%) and 240Pu (0.3 at%) was obtained without Am removal procedure. Meanwhile, 12.0 mg of Cm oxalate (99.8 at% over actinides) was obtained with the procedure including Am removals. Both of the obtained Cm oxalate sample were supplied for the syntheses and measurements of the thermochemical properties of curium compounds.

ジャーナルJournal of Radioanalytical and Nuclear Chemistry
出版ステータスPublished - 2013 6

ASJC Scopus subject areas

  • 分析化学
  • 原子力エネルギーおよび原子力工学
  • 放射線学、核医学およびイメージング
  • 汚染
  • 分光学
  • 公衆衛生学、環境および労働衛生
  • 健康、毒物学および変異誘発


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