Self-assembly of oligo(ethylene oxide)-linked diammonium ions with polyoxometalates into ordered polyhedron nanocrystals in aqueous media

Keita Ishiba, Daisuke Kichise, Hiroaki Iguchi, Masa Aki Morikawa, Nobuo Kimizuka

研究成果: Article査読

抄録

Self-assembly of Keggin-type polyoxometalates (POMs) with diammonium ions containing oligo(ethylene oxide) units form parallelepiped or octahedral nanocrystals. These structures are tunable depending on the chemical structure of the ammonium ions and preparative conditions. The ether linkages in these ammonium ions exert conformational flexibility, which is essential to achieve long-range regular molecular alignments in the nanocrystals.

本文言語English
ページ(範囲)430-433
ページ数4
ジャーナルChemistry Letters
46
4
DOI
出版ステータスPublished - 2017
外部発表はい

ASJC Scopus subject areas

  • 化学 (全般)

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