Self-Assembled molecular nanowires of 6,13-Bis(methylthio)pentacene: Growth, electrical properties, and applications

We demonstrate a comprehensive study of self-assembled molecular nanowire, including molecular design, one-dimensional crystal growth, resistivity measurement of individual wire, and application to a field-effect transistor. Appropriate molecular design and control of interfacial interactions lead to single crystalline wire growth with an extensive π-stacking motif. Resistivity measurements of an individual molecular wire indicate that these structural features are advantageous for electrical transport. Finally, field-effect transistors with single- and double- wire channels were fabricated to give some indication of the potential application of the molecular wires.