Selective transfer semihydrogenation of alkynes with nanoporous gold catalysts

Yogesh S. Wagh, Naoki Asao

    研究成果: Article査読

    48 被引用数 (Scopus)

    抄録

    A facile, highly chemo- and stereoselective transfer semihydrogenation of alkynes to Z-olefins has been achieved by use of unsupported nanoporous gold (AuNPore) as a heterogeneous catalyst together with formic acid as a hydrogen donor. A variety of terminal/internal and aromatic/aliphatic alkynes were reduced to the corresponding alkenes in high chemical yields with good functional-group tolerance. The catalyst is robust enough to be reused without leaching.

    本文言語English
    ページ(範囲)847-851
    ページ数5
    ジャーナルJournal of Organic Chemistry
    80
    2
    DOI
    出版ステータスPublished - 2015 1 16

    ASJC Scopus subject areas

    • Organic Chemistry

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