Selective impurity segregation at a near-∑5 grain boundary in MgO

Mitsuhiro Saito, Zhongchang Wang, Yuichi Ikuhara

    研究成果: Article査読

    11 被引用数 (Scopus)

    抄録

    Grain boundaries (GBs) together with their associated impurity segregation often affect or alter properties of many polycrystalline materials. However, their atomic-scale structures remain difficult to resolve spatially, especially for those with an orientation misalignment. Here, we apply a bicrystal technique to fabricate the near-∑5 GBs of MgO with a misalignment angle from the exact ∑5 orientation relationship and show an unexpected selective impurity segregation behavior at this GB. We find that the near-∑5 GB comprises an alternating array of five exact ∑5 GB structural units and one deformed ∑17 GB unit, and interestingly that the Ca and Ti impurities are co-segregated to the ∑5 GB structural units, yet are not to the deformed ∑17 GB structural units. The findings are important for the understanding of GBs with a misalignment and impurity segregation and for correlating structures with properties in polycrystalline materials.

    本文言語English
    ページ(範囲)3956-3961
    ページ数6
    ジャーナルJournal of Materials Science
    49
    11
    DOI
    出版ステータスPublished - 2014 6月

    ASJC Scopus subject areas

    • 材料科学(全般)
    • 材料力学
    • 機械工学

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