Selective electrocatalytic oxidation of primary and secondary alcohols mediated by decahydroquinolinyl-N-oxyl radical

Yoshitomo Kashiwagi, Futoshi Kurashima, Jun Ichi Anzai, Tesuo Osa

研究成果: Article査読

5 被引用数 (Scopus)

抄録

(±)-cis,cis-4-Benzoyloxy-2,2,8a-trimethyldecahydroquinolinyl-N-oxyl reveals a reversible redox peak whose oxidation potential is at + 0.67 V vs. Ag/AgCl. The compound catalyzed the selective oxidation reactions of primary and secondary alcohols to aldehydes and ketones, respectively, in high current efficiency (86.492.7%) and selectivity (100%).

本文言語English
ページ(範囲)1945-1948
ページ数4
ジャーナルHeterocycles
51
8
DOI
出版ステータスPublished - 1999 8 1

ASJC Scopus subject areas

  • Analytical Chemistry
  • Pharmacology
  • Organic Chemistry

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