Selective electrocatalytic oxidation of amines mediated by decahydroquinolinyl-N-oxyl radical

Yoshitomo Kashiwagi, Futoshi Kurashima, Chikara Kikuchi, Jun Ichi Anzai, Osa Tetsuo

研究成果: Article査読

4 被引用数 (Scopus)

抄録

Electrocatalytic oxidation of amines was studied using (±)trans, cis-4- benzoyloxy-2,2, 8a-trimethyldecahydroquinolinyl-N-oxyl. The reaction with amines led to direct formation of carbonyl compounds in aqueous media in adequate conversion (> 78 %), high current efficiency (> 90 %) and high selectivity (100 %). Under anhydrous conditions, primary amines were also oxidized to the corresponding nitriles in satisfactory conversion (> 76 %), high current efficiency (> 89 %) and high selectivity (> 95 %).

本文言語English
ページ(範囲)1583-1587
ページ数5
ジャーナルHeterocycles
53
7
DOI
出版ステータスPublished - 2000 7 1

ASJC Scopus subject areas

  • 分析化学
  • 薬理学
  • 有機化学

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