抄録
Electrocatalytic oxidation of amines was studied using (±)trans, cis-4- benzoyloxy-2,2, 8a-trimethyldecahydroquinolinyl-N-oxyl. The reaction with amines led to direct formation of carbonyl compounds in aqueous media in adequate conversion (> 78 %), high current efficiency (> 90 %) and high selectivity (100 %). Under anhydrous conditions, primary amines were also oxidized to the corresponding nitriles in satisfactory conversion (> 76 %), high current efficiency (> 89 %) and high selectivity (> 95 %).
本文言語 | English |
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ページ(範囲) | 1583-1587 |
ページ数 | 5 |
ジャーナル | Heterocycles |
巻 | 53 |
号 | 7 |
DOI | |
出版ステータス | Published - 2000 7 1 |
ASJC Scopus subject areas
- Analytical Chemistry
- Pharmacology
- Organic Chemistry