Rotational effect on SRVL nonradiative transitions: Linewidth and Coriolis coupling

H. Kono, S. H. Lin, E. W. Schlag

研究成果: Article査読

13 被引用数 (Scopus)

抄録

In the present paper, we discuss the rotational effect on interval conversion due to the linewidths and the Coriolis coupling in the final electronic state. For a formaldehyde model system, some numerical results of the rotational effect will be reported. It will be seen that the Coriolis coupling plays an important role in small linewidth cases. The numerical results also include the effect of the vibration-rotation coupling through the change of moments of inertia; the change of the geometry shifts between two electronic states due to this coupling is calculated numerically.

本文言語English
ページ(範囲)4474-4483
ページ数10
ジャーナルThe Journal of Chemical Physics
77
9
DOI
出版ステータスPublished - 1982 1 1

ASJC Scopus subject areas

  • 物理学および天文学(全般)
  • 物理化学および理論化学

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