Rhodium-catalyzed organothio exchange reaction of α-organothioketones with disulfides

Mieko Arisawa, Fumihiko Toriyama, Masahiko Yamaguchi

研究成果: Article

8 引用 (Scopus)

抜粋

RhH(PPh3)4 and 1,2-bis(diphenylphosphino)ethane (dppe) catalyzed the organothio exchange reaction of α-organothioketones and organic disulfides. The reaction was affected by the structure of the substrate: α-phenylthio and α-alkylthio aryl ketones reacted effectively with diaryl and dialkyl disulfides; α-phenylthio dialkyl ketones reacted with diaryl disulfides but not with dialkyl disulfides; diaryl disulfides with electron-donating p-substituents were more reactive than those with electron-withdrawing p-substituents.

元の言語English
ページ(範囲)1349-1352
ページ数4
ジャーナルChemical and Pharmaceutical Bulletin
58
発行部数10
DOI
出版物ステータスPublished - 2010 10

ASJC Scopus subject areas

  • Chemistry(all)
  • Drug Discovery

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