Rhodium-catalyzed conjugate addition of aryl- and alkenyl-stannanes to α,β-unsaturated carbonyl compounds

Shuichi Oi, Mitsutoshi Moro, Hisanori Ito, Yoshio Honma, Sotaro Miyano, Yoshio Inoue

研究成果: Article

93 引用 (Scopus)

抜粋

The addition of aryl- or alkenyl-trimethylstannanes to α,β-unsaturated carbonyl compounds in the presence of a catalytic amount of a cationic rhodium complex ([Rh(cod)(MeCN)2]BF4) and water to afford the conjugate addition products in good yields was examined. It was observed that addition of water was necessary for the reaction to proceed smoothly. The aryl- or alkenyl-rhodium complex, which is generated by the transmetalation from the organotin compound, is considered to be the active catalytic species.

元の言語English
ページ(範囲)91-97
ページ数7
ジャーナルTetrahedron
58
発行部数1
DOI
出版物ステータスPublished - 2002 1 1

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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