Rh(III)-catalyzed regioselective functionalization of C-H bonds of naphthylcarbamates for oxidative annulation with alkynes

Xuan Zhang, Weili Si, Ming Bao, Naoki Asao, Yoshinori Yamamoto, Tienan Jin

研究成果: Article査読

58 被引用数 (Scopus)

抄録

A Rh(III)-catalyzed highly efficient and regioselective functionalization of diverse C-H bonds of naphthylcarbamates for oxidative annulation with alkynes has been developed. The annulation with a neutral rhodium catalyst system proceeds through peri C-H bond functionalization of arylcarbamates to give benzoquinoline derivatives, while with a cationic rhodium catalyst system it proceeds through ortho C-H functionalization of arylcarbamates to furnish benzoindole derivatives.

本文言語English
ページ(範囲)4830-4833
ページ数4
ジャーナルOrganic letters
16
18
DOI
出版ステータスPublished - 2014 9 19

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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