RhCl3-catalyzed disulfide exchange reaction using water solvent in homogeneous and heterogeneous systems

Mieko Arisawa, Atsushi Suwa, Masahiko Yamaguchi

研究成果: Article査読

22 被引用数 (Scopus)

抄録

RhCl3 catalyzed the alkylthio exchange reaction of hydrophilic disulfides in water under homogeneous conditions, and equilibrium was attained in several hours. The reaction was applied to the exchange of unprotected glutathione disulfide. The reaction of dimethyl disulfide and hydrophilic disulfides under heterogeneous conditions also proceeded effectively. The mechanism turned out to be dependent on the water solubility of the substrates: The reaction of bis(3-hydroxypropyl) disulfide took place in the dimethyl disulfide phase, whereas the reaction of bis(6-aminohexyl) disulfide dihydrochloride proceeded in the water phase.

本文言語English
ページ(範囲)1159-1168
ページ数10
ジャーナルJournal of Organometallic Chemistry
691
6
DOI
出版ステータスPublished - 2006 3 1

ASJC Scopus subject areas

  • 生化学
  • 物理化学および理論化学
  • 有機化学
  • 無機化学
  • 材料化学

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