Reversible Thermal and Photochemical Interconversion between Cis and Trans Isomers of the Silylene-Bridged Diiron Complex Cp′2Fe2(CO)3(μ-SiHTol) (Cp′ = η-C5Me5, Tol = p-CH3C6H4)

Yasuro Kawano; Hiromi Tobita; Hiroshi Ogino

doi:10.1021/om00038a002

Reversible Thermal and Photochemical Interconversion between Cis and Trans Isomers of the Silylene-Bridged Diiron Complex Cp′₂Fe₂(CO)₃(μ-SiHTol) (Cp′ = η-C₅Me₅, Tol = p-CH₃C₆H₄)

Yasuro Kawano, Hiromi Tobita, Hiroshi Ogino

高度教養教育・学生支援機構（機構レベル所属のみ）

研究成果: Article › 査読

22 被引用数 (Scopus)

抄録

Isomerization between cis-Cp′₂Fe₂(CO)₃(μ- SiHTol) (cis-1; Cp′= η-C₅Me₅, Tol = p-CH₃C₆H₄) and trans-1 was found to occur both thermally and photochemically. The composition in the thermal equilibrium state (cis-1:trans-1 = 2:98 in cyclohexane-d₁₂) is considerably different from that in the photostationary state (cis-1: trans-1 = 70:30).

本文言語	English
ページ（範囲）	499-500
ページ数	2
ジャーナル	Organometallics
巻	11
号	2
DOI	https://doi.org/10.1021/om00038a002
出版ステータス	Published - 1992 2月 1

ASJC Scopus subject areas

物理化学および理論化学
有機化学
無機化学

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10.1021/om00038a002

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「Reversible Thermal and Photochemical Interconversion between Cis and Trans Isomers of the Silylene-Bridged Diiron Complex Cp′₂Fe₂(CO)₃(μ-SiHTol) (Cp′ = η-C₅Me₅, Tol = p-CH₃C₆H₄)」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル

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abstract = "Isomerization between cis-Cp′2Fe2(CO)3(μ- SiHTol) (cis-1; Cp′= η-C5Me5, Tol = p-CH3C6H4) and trans-1 was found to occur both thermally and photochemically. The composition in the thermal equilibrium state (cis-1:trans-1 = 2:98 in cyclohexane-d12) is considerably different from that in the photostationary state (cis-1: trans-1 = 70:30).",

author = "Yasuro Kawano and Hiromi Tobita and Hiroshi Ogino",

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T1 - Reversible Thermal and Photochemical Interconversion between Cis and Trans Isomers of the Silylene-Bridged Diiron Complex Cp′2Fe2(CO)3(μ-SiHTol) (Cp′ = η-C5Me5, Tol = p-CH3C6H4)

AU - Kawano, Yasuro

AU - Tobita, Hiromi

AU - Ogino, Hiroshi

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N2 - Isomerization between cis-Cp′2Fe2(CO)3(μ- SiHTol) (cis-1; Cp′= η-C5Me5, Tol = p-CH3C6H4) and trans-1 was found to occur both thermally and photochemically. The composition in the thermal equilibrium state (cis-1:trans-1 = 2:98 in cyclohexane-d12) is considerably different from that in the photostationary state (cis-1: trans-1 = 70:30).

AB - Isomerization between cis-Cp′2Fe2(CO)3(μ- SiHTol) (cis-1; Cp′= η-C5Me5, Tol = p-CH3C6H4) and trans-1 was found to occur both thermally and photochemically. The composition in the thermal equilibrium state (cis-1:trans-1 = 2:98 in cyclohexane-d12) is considerably different from that in the photostationary state (cis-1: trans-1 = 70:30).

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