Reversible Destabilization of UV-Responsive Polymer Particles (Latex) using a Photoresponsive Surfactant

Florent Jasinski, Thiago R. Guimarães, Samantha David, Caroline Suniary, Toby Funston, Yutaka Takahashi, Yukishige Kondo, Per B. Zetterlund

研究成果: Article査読

8 被引用数 (Scopus)

抄録

Production of aqueous dispersions of polymeric nanoparticles via heterogeneous radical polymerization in emulsion-type systems is of enormous commercial importance. The ability to reversibly destabilize such a latex is highly desirable, for example, to save transportation costs. Herein, a method for synthesis of photo-responsive polymer latexes that can be destabilized (leading to sedimentation) by only using UV irradiation (no addition of chemicals or change in the experimental conditions) and subsequently redispersed by stirring under visible light irradiation is described. The destabilization/redispersion mechanism relies on photoinduced trans-cis isomerization of the cationic diazene surfactant 2-(4-(4-butylphenyl)diazenylphenoxy)ethyltrimethylammonium bromide (C4AzoTAB) used in conjunction with the anionic surfactant sodium dodecyl sulfate. It is demonstrated that reversible destabilization can be achieved very rapidly (90 s residence time) employing continuous flow technology.

本文言語English
論文番号1900355
ジャーナルMacromolecular Rapid Communications
40
22
DOI
出版ステータスPublished - 2019 11月 1

ASJC Scopus subject areas

  • 有機化学
  • ポリマーおよびプラスチック
  • 材料化学

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