Reverse spin transition triggered by a structural phase transition

Shinya Hayami, Yuji Shigeyoshi, Motoko Akita, Katsuya Inoue, Kenichi Kato, Keiichi Osaka, Masaki Takata, Ryo Kawajiri, Tadaoki Mitani, Yonezo Maeda

研究成果: Article査読

130 被引用数 (Scopus)

抄録

(Figure Presented) Reverse spin crossover (RSCO), the reversible spin transition from the high- to the low-spin state upon heating, was observed in [Co(Cn-terpy)2](BF4)2 (C n-terpy = terpyridine) equipped with a long alkoxy chain (AC) of n = 14 or 16 methylene units (see picture). The wide thermal hysteresis of the RSCO around room temperature could allow such compounds to be used as molecular switches.

本文言語English
ページ(範囲)4899-4903
ページ数5
ジャーナルAngewandte Chemie - International Edition
44
31
DOI
出版ステータスPublished - 2005 8月 5
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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