Removal of inelastic scattering part from Ti2p XPS spectrum of TiO2 by deconvolution method using O1s as response function

Masaoki Oku, Hideyuki Matsuta, Kazuaki Wagatsuma, Yoshio Waseda, Shigemi Kohiki

研究成果: Article査読

44 被引用数 (Scopus)

抄録

Ti2p and O1s XPS spectra of a clean surface of single crystal TiO2 fractured in situ were taken to study the removal of the inelastic scattering part from the Ti2p spectrum. The features of inelastic scattering peaks in EELS were more influenced by surface than O1s XPS. It indicates that O1s XPS is proper as the response function to deconvolute a Ti2p spectrum. FWHM of the non-energy loss peak of Ti2p3/2 is smaller than that of O1s. When the raw O1s spectrum is used as the response function, the deconvoluted spectrum has negative intensity values in some regions and beat waves. The replacement of the non-energy loss peak of O1s with narrower Gaussian peak takes off the beat waves. Peak separation of the deconvoluted spectrum reveals that it has six peaks. Two of them are main peaks of Ti2p3/2 and 2p1/2. The others are classified into two kinds of satellite peaks, whose energy separation from the main peaks are 3 and 13 eV. Although the latter satellites have been discussed by many authors, the former satellites are first reported here.

本文言語English
ページ(範囲)211-218
ページ数8
ジャーナルJournal of Electron Spectroscopy and Related Phenomena
105
2-3
DOI
出版ステータスPublished - 1999 12

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 放射線
  • 原子分子物理学および光学
  • 凝縮系物理学
  • 分光学
  • 物理化学および理論化学

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