Relay catalysis using a rhodium complex/chiral Brønsted acid binary system: Enantioselective reduction of a carbonyl ylide as the reactive intermediate

Masahiro Terada, Yasunori Toda

研究成果: Article査読

66 被引用数 (Scopus)

抄録

Pass the baton: A one-pot relay catalysis for a carbonyl ylide formation/enantioselective reduction sequence using a dirhodium(II) tetracarboxylate and chiral phosphoric acid catalyst system is described. The four-step transformation involves a rhodium carbene complex, a carbonyl ylide, and an isobenzopyrylium intermediate, the enantioselective reduction of which yields isochromanone derivatives in good yield with high selectivity.

本文言語English
ページ(範囲)2093-2097
ページ数5
ジャーナルAngewandte Chemie - International Edition
51
9
DOI
出版ステータスPublished - 2012 2 27

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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