Relay catalysis by a metal-complex/brønsted acid binary system in a tandem isomerization/carbon-carbon bond forming sequence

Keiichi Sorimachi, Masahiro Terada

研究成果: Article査読

138 被引用数 (Scopus)

抄録

A one-pot tandem isomerization/carbon-carbon bond forming sequence catalyzed by a ruthenium complex/Brønsted acid binary system is demonstrated. The method enables the use of readily available allylamides to deliver reactive imines under relay catalysis using a binary catalytic system. Subsequent Brønsted acid catalyzed carbon-carbon bond forming reactions of the generated imines with nucleophilic components afforded Friedel-Crafts and Mannich products in good yields.

本文言語English
ページ(範囲)14452-14453
ページ数2
ジャーナルJournal of the American Chemical Society
130
44
DOI
出版ステータスPublished - 2008 11 5

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)
  • 生化学
  • コロイド化学および表面化学

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