Relationship between the time, yield, and enantiomeric excess of asymmetric autocatalysis of chiral 2-alkynyl-5-pyrimidyl alkanol with amplification of enantiomeric excess

Itaru Sato, Daisuke Omiya, Hiroyoshi Igarashi, Keiichi Kato, Yoshihiro Ogi, Koichi Tsukiyama, Kenso Soai

研究成果: Article査読

111 被引用数 (Scopus)

抄録

Experimental and kinetic analysis of asymmetric autocatalysis with amplification of ee in the enantioselective addition of diisopropylzinc to 2-alkynylpyrimidine-5-carbaldehyde using chiral 2-alkynyl-5-pyrimidyl alkanol with low ee's are described.

本文言語English
ページ(範囲)975-979
ページ数5
ジャーナルTetrahedron Asymmetry
14
8
DOI
出版ステータスPublished - 2003 4 18

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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