TY - JOUR
T1 - Regioselective synthesis of several heterocyclic fused azepines using diisobutylaluminum hydride
AU - Cho, Hidetsura
AU - Murakami, Kengo
AU - Nakanishi, Hiroyuki
AU - Isoshima, Hirotaka
AU - Hayakawa, Kazuhide
AU - Uchida, Itsuo
PY - 1998/1/1
Y1 - 1998/1/1
N2 - 5,6,7,8-Tetrahydrothieno[3,2-b]azepine,5,6,7,8-tetrahydro-1H-furo[3,2-b] azepine, and 1,4,5,6,7,8-hexahydropyrrolo[3,2-b]azepine were synthesized by the ring expansion reaction of heterocyclic fused cyclohexanone oximes with diisobutylaluminum hydride (DIBAH). The mechanism of the reaction was different from that of Beckmann rearrangement.
AB - 5,6,7,8-Tetrahydrothieno[3,2-b]azepine,5,6,7,8-tetrahydro-1H-furo[3,2-b] azepine, and 1,4,5,6,7,8-hexahydropyrrolo[3,2-b]azepine were synthesized by the ring expansion reaction of heterocyclic fused cyclohexanone oximes with diisobutylaluminum hydride (DIBAH). The mechanism of the reaction was different from that of Beckmann rearrangement.
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U2 - 10.3987/COM-98-8104
DO - 10.3987/COM-98-8104
M3 - Article
AN - SCOPUS:0000766506
VL - 48
SP - 919
EP - 927
JO - Heterocycles
JF - Heterocycles
SN - 0385-5414
IS - 5
ER -