Regioselective hydroesterification of styrene catalyzed by cationic palladium(II) complexes under mild conditions

S. Oi, M. Nomura, T. Aiko, Y. Inoue

研究成果: Article査読

93 被引用数 (Scopus)

抄録

The cationic palladium(II) complex [Pd(MeCN)2(PPh3)2](BF4)2 was found to be an active catalyst for hydroesterification of styrene using CO and methanol under very mild conditions. The system, Pd(OAc)2-PPh3-p- toluenesulfonic acid, which should give rise to a cationic species in situ, was also effective to produce the branched ester regioselectively in an excellent yield at ambient temperature. Asymmetric hydroesterification of styrene by the use of chiral phosphines as ligands was also studied.

本文言語English
ページ(範囲)289-295
ページ数7
ジャーナルJournal of Molecular Catalysis A: Chemical
115
2
DOI
出版ステータスPublished - 1997 1 29

ASJC Scopus subject areas

  • Catalysis
  • Process Chemistry and Technology
  • Physical and Theoretical Chemistry

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