Regio- and stereoselective additions of diphenyldithiophosphinic acid to N-(1-alkynyl)amides and 1-alkynyl sulfides

Shigenari Kanemura, Azusa Kondoh, Hiroto Yasui, Hideki Yorimitsu, Koichiro Oshima

研究成果: Article

17 引用 (Scopus)

抜粋

Treatment of N-(l-alkynyl)amides and 1-alkynyl sulfides with diphenyldithiophosphinic acid affords (E)-ketene N,S-acetals and S.S-acetals, respectively. The addition reactions proceed in syn fashions, which consist of protonation of the electron-rich alkynes and the following nucleophilic addition of diphenyldithiophosphinate anion to the resulting cationic intermediates.

元の言語English
ページ(範囲)506-514
ページ数9
ジャーナルBulletin of the Chemical Society of Japan
81
発行部数4
DOI
出版物ステータスPublished - 2008 12 1
外部発表Yes

ASJC Scopus subject areas

  • Chemistry(all)

フィンガープリント Regio- and stereoselective additions of diphenyldithiophosphinic acid to N-(1-alkynyl)amides and 1-alkynyl sulfides' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用