Redox potentials of a series of lanthanide-bisphthalocyanine sandwich complexes

Hideo Konami, Masahiro Hatano, Nagao Kobayashi, Tetsuo Osa

研究成果: Article査読

90 被引用数 (Scopus)

抄録

Electrochemical measurements on a series of [NBu4][Ln(III)Pc2] ([NBu4]=tetra(n-butyl)ammonium; Ln=Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Tm, Er, Yb, and Lu; Pc=phthalocyanine) are reported. The first and second oxidation potentials decrease linearly with a decrease in ionic radii of the center metals, while the reduction potentials showed no observable change. A few complexes of earlier lanthanides showed irreversible redox couples at the second oxidation potentials.

本文言語English
ページ(範囲)397-400
ページ数4
ジャーナルChemical Physics Letters
165
5
DOI
出版ステータスPublished - 1990 1 26

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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