Recoil implantation reaction in geometrical isomers of tris/benzoylacetonato/chromium/III/

T. Sekine, K. Yoshihara

研究成果: Article査読

5 被引用数 (Scopus)

抄録

Hot atom chemical reaction by50Cr/n, γ/51Cr and52Cr/γ, n/51Cr reactions, and recoil implantation reaction by51V/p, n/51Cr reaction were investigated using geometrical isomers /mer and fac/ of tris/benzoylacetonato/ chromium/III/ /Cr/ba/3/. The production of counter isomer was observed for both mer- and fac-targets, although the yield of labelled parent isomer was larger. The observed mer/fac yield ratio suggests that the main formation mechanism of51Cr/ba/3 is the reaction of ba- and Cr/ba/2+ which has the same geometrical configuration of target complex, and the substitution reaction of central metal atom by recoil51Cr. Furthermore, implantation gave rise to a much higher yield of labelled Cr/ba/3 compared to the case of in situ nuclear recoils.

本文言語English
ページ(範囲)137-147
ページ数11
ジャーナルJournal of Radioanalytical and Nuclear Chemistry Letters
118
2
DOI
出版ステータスPublished - 1987 7 1

ASJC Scopus subject areas

  • Analytical Chemistry
  • Nuclear Energy and Engineering
  • Radiology Nuclear Medicine and imaging
  • Pollution
  • Spectroscopy
  • Public Health, Environmental and Occupational Health
  • Health, Toxicology and Mutagenesis

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