Recent progress on catalytic [1,3]-oxygen rearrangement reactions from nitrogen to carbon atoms

研究成果: Review article査読

10 被引用数 (Scopus)

抄録

[1,3]-Rearrangement reactions of an oxygen atom from a nitrogen atom to a carbon atom is an ideal way to synthesize highly elaborate molecules in which nitrogen and oxygen functionalities are vicinally arranged. Recently, it has been disclosed that this intriguing transformation takes place in the presence of Lewis acidic metal catalysts. In this digest, we summarize recent findings on the catalytic [1,3]-oxygen rearrangement reactions, such as direct [1,3]-rearrangement of N-oxygenated enamines and anilines, as well as π-acidic metal-catalyzed cascade reaction involving the [1,3]-rearrangement process.

本文言語English
ページ(範囲)689-698
ページ数10
ジャーナルTetrahedron Letters
60
10
DOI
出版ステータスPublished - 2019 3月 7

ASJC Scopus subject areas

  • 生化学
  • 創薬
  • 有機化学

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