Reactivity of phosphasilametallacyclopropane toward substrates with polarized E-H bonds (E = O, N, S, and P): Formation and structures of ring-opening products

Masaaki Okazaki, Kyeong A. Jung, Hiromi Tobita

研究成果: Article査読

11 被引用数 (Scopus)

抄録

Treatment of a three-membered metallacycle Cp*(CO)Fe{k 2(Si,P)-SiMe2PPh2} (1) with substrates of the type RnEH (ERn = OH, OMe, OiBu, OPh, S pTol, NEt2, NPhH, PPh2, and PPhH) results in the instantaneous formation of the ring-opening products Cp*(CO)Fe- (PPh2H)(SiMe2ERn). In these reactions, 1,2-additdon of the substrates occurs exclusively across the silicon-phosphorus bond in 1. The structures of the products have been unequivocally determined by spectroscopic data and X-ray diffraction analysis.

本文言語English
ページ(範囲)659-664
ページ数6
ジャーナルOrganometallics
24
4
DOI
出版ステータスPublished - 2005 2 14

ASJC Scopus subject areas

  • 物理化学および理論化学
  • 有機化学
  • 無機化学

フィンガープリント

「Reactivity of phosphasilametallacyclopropane toward substrates with polarized E-H bonds (E = O, N, S, and P): Formation and structures of ring-opening products」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル