Barrelene-type dialumanes bearing bulky aryl substituents were synthesized, and their reactivity as synthetic equivalents of the corresponding dialumenes was elucidated. Reaction of the barrelene-type dialumanes with [Pt(PCy3)2] afforded platinum complexes of the corresponding alumylene (ArAl:). Structures of the newly obtained cyclic compounds containing an Al-Al bond and the platinum complexes were determined.
|ジャーナル||Phosphorus, Sulfur and Silicon and the Related Elements|
|出版ステータス||Published - 2016 4月 2|
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