Reaction of a dialumene-benzene adduct with diphenylacetylene: Formation of 3,4-dialuminacyclobutene and 5,6-dialuminabicyclo[2.1.1]hex-2-ene derivatives

Tomohiro Agou, Koichi Nagata, Takahiro Sasamori, Norihiro Tokitoh

研究成果: Article

8 引用 (Scopus)

抜粋

Reaction of a dialumene-benzene adduct bearing bulky aryl substituents with diphenylacetylene was found to give a novel 5,6-dialuminabicyclo[2.1.1]hex-2-ene derivative in addition to the 3,4-dialuminacyclobutene derivative, the formal [2+2]cycloadduct of an intermediary dialumene with diphenylacetylene. The molecular structure of the newly obtained 5,6-dialuminabicyclo[2.1.1]hex-2-ene has been elucidated by X-ray crystallographic analysis.

元の言語English
ページ(範囲)3099-3101
ページ数3
ジャーナルChemistry - An Asian Journal
9
発行部数11
DOI
出版物ステータスPublished - 2014 11
外部発表Yes

ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry

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