TY - JOUR
T1 - Reaction of 2,4-di-t-butyl-6-methylphenylphosphonous dichloride with chloroform in the presence of lithium diisopropylamide
AU - Yoshifuji, Masaaki
AU - Ito, Shigekazu
AU - Toyota, Kozo
AU - Yasunami, Masafumi
PY - 1996/1/1
Y1 - 1996/1/1
N2 - 2,4-Di-t-butyl-6-methylphenylphosphonous dichloride reacted with chloroform in the presence of lithium diisopropylamide to give (2,4-di-t-butyl-6-methylphenyl)(dichloromethyl)(1,2,2-trichloroethenyl) phosphine. The structure of this phosphine was analyzed by X-ray crystallography. This phosphine further reacted with butyllithium to give (1-butylpentylidene)(2,4-di-t-butyl-6-methylphenyl)phosphine bearing a low-coordinated phosphorus atom.
AB - 2,4-Di-t-butyl-6-methylphenylphosphonous dichloride reacted with chloroform in the presence of lithium diisopropylamide to give (2,4-di-t-butyl-6-methylphenyl)(dichloromethyl)(1,2,2-trichloroethenyl) phosphine. The structure of this phosphine was analyzed by X-ray crystallography. This phosphine further reacted with butyllithium to give (1-butylpentylidene)(2,4-di-t-butyl-6-methylphenyl)phosphine bearing a low-coordinated phosphorus atom.
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U2 - 10.1002/(SICI)1098-1071(199601)7:1<23::AID-HC4>3.0.CO;2-3
DO - 10.1002/(SICI)1098-1071(199601)7:1<23::AID-HC4>3.0.CO;2-3
M3 - Article
AN - SCOPUS:0004602575
VL - 7
SP - 23
EP - 27
JO - Heteroatom Chemistry
JF - Heteroatom Chemistry
SN - 1042-7163
IS - 1
ER -