Reaction of 2,4-di-t-butyl-6-methylphenylphosphonous dichloride with chloroform in the presence of lithium diisopropylamide

Masaaki Yoshifuji, Shigekazu Ito, Kozo Toyota, Masafumi Yasunami

研究成果: Article査読

5 被引用数 (Scopus)

抄録

2,4-Di-t-butyl-6-methylphenylphosphonous dichloride reacted with chloroform in the presence of lithium diisopropylamide to give (2,4-di-t-butyl-6-methylphenyl)(dichloromethyl)(1,2,2-trichloroethenyl) phosphine. The structure of this phosphine was analyzed by X-ray crystallography. This phosphine further reacted with butyllithium to give (1-butylpentylidene)(2,4-di-t-butyl-6-methylphenyl)phosphine bearing a low-coordinated phosphorus atom.

本文言語English
ページ(範囲)23-27
ページ数5
ジャーナルHeteroatom Chemistry
7
1
DOI
出版ステータスPublished - 1996 1月 1

ASJC Scopus subject areas

  • 化学 (全般)

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