Raman Scattering from Co-substituted YBa2Cu3-xCoxO6+y Superconductors

Hirotaka Fujimori, Masato Kakihana, Masatomo Yashima, Masahiro Yoshimura, Hiromasa Mazaki, Hiroshi Yasuoka

研究成果: Article査読

抄録

A systematic Micro-Raman spectroscopic investigation has been performed on YBa2Cu3-xCoxO6+y ceramic samples of different Co content x in the interval 0≤x≤1 which are prepared by a polymerized complex method. With increasing Co content an evolution of the defect induced Raman scattering of the CuO chain modes (550-650 cm-1 region) has been observed. The intensity of the defect modes has increased with increasing Co concentration, which has in turn suggested increased disordering of oxygen in the based (Cu/Co)-Oy plane. It has been infered from Raman spectroscopic results that the CuO chain disorder is closely related to Tc and a certain minimal size of the oxygen disordered (or ordered) domain is needed for a decrease in Tc (or the appearance of superconductivity).

本文言語English
ページ(範囲)792-797
ページ数6
ジャーナルjournal of the japan society of powder and powder metallurgy
42
7
DOI
出版ステータスPublished - 1995
外部発表はい

ASJC Scopus subject areas

  • 機械工学
  • 産業および生産工学
  • 金属および合金
  • 材料化学

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