Quasi-isotropic fragmentation of PF 5 following P 2p photoabsorption

K. Ueda, Y. Muramatsu, Y. Shimizu, H. Chiba, Y. Sato, M. Kitajima, H. Tanaka, H. Nakamatsu

研究成果: Article査読

2 被引用数 (Scopus)

抄録

We have investigated the P 2p photoabsorption of a D3h symmetry molecule PF5 using angle-resolved ion yield spectroscopy and analyzed it with the help of first-principles calculations within the framework of the DV-Xα method. Nearly isotropic ionic fragmentation is observed irrespective of the symmetries of the excited states and interpreted using a model in which two axial P-F bonds and three equatorial P-F bonds are assumed to have roughly the same rupture probabilities via P 2p Auger decay.

本文言語English
ページ(範囲)45-50
ページ数6
ジャーナルChemical Physics Letters
308
1-2
DOI
出版ステータスPublished - 1999 7 16

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

フィンガープリント 「Quasi-isotropic fragmentation of PF <sub>5</sub> following P 2p photoabsorption」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

引用スタイル