[{[Pt(en)2][PtX2(en)2]} 3][{(MX5)X3}2]·12H 2O: Quasi-one-dimensional halogen-bridged PtII-Pt IV mixed-valence compounds with magnetic counteranions

Masahiro Yamashita, Daisuke Kawakami, Satoshi Matsunaga, Yoshio Nakayama, Mari Sasaki, Shinya Takaishi, Fumiyasu Iwahori, Hitoshi Miyasaka, Ken Ichi Sugiura, Yoshiki Wada, Hiroshi Miyamae, Hiroyuki Matsuzaki, Hiroshi Okamoto, Hisaaki Tanaka, Kazuhiro Marumoto, Shinichi Kuroda

研究成果: Article査読

20 被引用数 (Scopus)

抄録

Attractive complexes: Hexagonal micropores similar to zeolites have been observed in mixed-valence PtII-PtIV compounds with magnetic counteranions (see X-ray crystal structure). The micropores contain 12 water molecules per molecular unit which can be desorbed by heating the complexes to 100 °C and re-adsorbed by cooling to 20 °C without affecting the skeletal structure.

本文言語English
ページ(範囲)4763-4767
ページ数5
ジャーナルAngewandte Chemie - International Edition
43
36
DOI
出版ステータスPublished - 2004 9 13

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

フィンガープリント

「[{[Pt(en)<sub>2</sub>][PtX<sub>2</sub>(en)<sub>2</sub>]} <sub>3</sub>][{(MX<sub>5</sub>)X<sub>3</sub>}<sub>2</sub>]·12H <sub>2</sub>O: Quasi-one-dimensional halogen-bridged Pt<sup>II</sup>-Pt <sup>IV</sup> mixed-valence compounds with magnetic counteranions」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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