Promoting effect of Mo on the hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol over Rh/SiO2

Shuichi Koso, Naoyuki Ueda, Yasunori Shinmi, Kazu Okumura, Tokushi Kizuka, Keiichi Tomishige

研究成果: Article査読

181 被引用数 (Scopus)

抄録

Addition of Mo to Rh/SiO2 promoted the hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol drastically. Addition of Re and W to Rh/SiO2 was also effective, but the promoting effect of Mo was more remarkable in terms of catalyst stability and high activity even at low reactant concentrations. Characterization of Rh-MoOx/SiO2 suggests that a partially reduced Mo species is attached to the surface of Rh metal particles. The synergy between the MoOx and the Rh metal surface results in a high chemoselectivity and activity in the hydrogenolysis of tetrahydrofurfuryl alcohol.

本文言語English
ページ(範囲)89-92
ページ数4
ジャーナルJournal of Catalysis
267
1
DOI
出版ステータスPublished - 2009 10月 1
外部発表はい

ASJC Scopus subject areas

  • 触媒
  • 物理化学および理論化学

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