Promoting effect of Mo on alcohol formation in hydroformylation of propylene and ethylene on Mo-Rh/SiO2

Keiichi Tomishige, Ippei Furikado, Takashi Yamagishi, Shin Ichi Ito, Kimio Kunimori

研究成果: Article査読

17 被引用数 (Scopus)

抄録

It is found that the addition of Mo to Rh/SiO2 (Mo-Rh/SiO 2) promoted alcohol formation in hydroformylation of propylene and ethylene, at the same time it drastically enhanced the activity of hydroformylation and hydrogenation. It is suggested that H2 adsorption sites, which are not inhibited by CO adsorption, are present on Mo-Rh/SiO2. The sites can cause high H2 activation, and it can be related to the additive effect of Mo in hydroformylation reactions.

本文言語English
ページ(範囲)15-21
ページ数7
ジャーナルCatalysis Letters
103
1-2
DOI
出版ステータスPublished - 2005 9 1
外部発表はい

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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