Preparation of 2-iodo-1,3-butadienes from 1-trimethylsilyl-2,3- butadienes and their functionalizations

Takashi Nishiyama, Tomoyuki Esumi, Yoshiharu Iwabuchi, Hiroshi Irie, Susumi Hatakeyama

研究成果: Article

28 引用 (Scopus)

抜粋

Successive treatment of 1-trimethylsilyl-2.3-butadienes with iodine and tetra-n-butylammonium fluoride in the same flask affords 2-iodo-1.3- butadienes in good yields and their palladium-catalyzed carbonylation and alkynylation allows introduction of ester and alkynyl groups to the 2- position bearing an iodine atom leading to various 2.3-disubstituted 1,3- butadienes.

元の言語English
ページ(範囲)43-46
ページ数4
ジャーナルTetrahedron Letters
39
発行部数1-2
DOI
出版物ステータスPublished - 1998 1 1
外部発表Yes

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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