Preparation and X‐ray crystal structure analysis of cis‐2, 4‐bis(2, 4, 6‐tri‐t‐butylphenyl)‐1, 2, 4‐oxadiphosphetane 2, 4‐disulfide and cis/trans isomerization of the corresponding 1, 2, 4‐thiadiphosphetane derivative

Kozo Toyota, Yasuhisa Ishikawa, Kotaro Shirabe, Masaaki Yoshifuji, Kengo Okada, Ken Hirotsu

研究成果: Article査読

8 被引用数 (Scopus)

抄録

1,3‐Bis(2,4,6‐tri‐t‐butylphenyl)‐1,3‐diphosphaallene (1) reacted with elemental sulfur under wet reaction conditions to give cis‐ and trans‐2,4‐bis(2,4,6‐tri‐t‐butylphenyl)‐1,2,4‐thiadiphosphetane 2,4‐disulfide (cis‐2 and trans‐2) and cis‐2,4‐bis(2,4,6‐tri‐t‐butylphenyl)‐1,2,4‐oxadiphosphetane 2,4‐disulfide (cis‐3). The structure of cis‐3 was determined by X‐ray crystallography, and the cis/trans isomerization of 2 was studied.

本文言語English
ページ(範囲)279-285
ページ数7
ジャーナルHeteroatom Chemistry
4
2-3
DOI
出版ステータスPublished - 1993 1 1

ASJC Scopus subject areas

  • Chemistry(all)

フィンガープリント 「Preparation and X‐ray crystal structure analysis of cis‐2, 4‐bis(2, 4, 6‐tri‐t‐butylphenyl)‐1, 2, 4‐oxadiphosphetane 2, 4‐disulfide and cis/trans isomerization of the corresponding 1, 2, 4‐thiadiphosphetane derivative」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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