Power of cooperativity: Lewis acid-Lewis base bifunctional asymmetric catalysis

Motomu Kanai, Nobuki Kato, Eiko Ichikawa, Masakatsu Shibasaki

研究成果: Review article査読

349 被引用数 (Scopus)

抄録

The concept of bifunctional asymmetric catalysis is very powerful for designing new enantioselective catalysts. We describe our investigation starting with the development of a BINOL-derived Lewis acid-Lewis base bifunctional asymmetric catalyst for cyanosilylation of aldehydes. The initial establishment of the concept was followed by the development of new sugar-derived catalysts that promote general catalytic enantioselective cyanosilylation of ketones. We also describe the catalytic enantioselective Reissert reaction of pyridine derivatives and Strecker reaction of ketoimines as recent advances in this field.

本文言語English
ページ(範囲)1491-1508
ページ数18
ジャーナルSynlett
10
DOI
出版ステータスPublished - 2005 6 17
外部発表はい

ASJC Scopus subject areas

  • 有機化学

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