Polyanionic hexagons: X 6 n- (X = Si, Ge)

研究成果: Review article査読

5 被引用数 (Scopus)

抄録

The paper reviews the polyanionic hexagons of silicon and germanium, focusing on aromaticity. The chair-like structures of hexasila- and hexagermabenzene are similar to a nonaromatic cyclohexane (CH 2) 6 and dissimilar to aromatic D 6h-symmetric benzene (CH) 6, although silicon and germanium are in the same group of the periodic table as carbon. Recently, six-membered silicon and germanium rings with extra electrons instead of conventional substituents, such as alkyl, aryl, etc., were calculated by us to have D 6h symmetry and to be aromatic. We summarize here our main findings and the background needed to reach them, and propose a synthetically accessible molecule.

本文言語English
ページ(範囲)1745-1762
ページ数18
ジャーナルSymmetry
2
4
DOI
出版ステータスPublished - 2010 12

ASJC Scopus subject areas

  • コンピュータ サイエンス(その他)
  • 化学(その他)
  • 数学 (全般)
  • 物理学および天文学(その他)

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