Pincer-type bis(carbene)-derived complexes of nickel(II): Synthesis, structure, and catalytic activity

Kiyofumi Inamoto, Jun ichi Kuroda, Eunsang Kwon, Kou Hiroya, Takayuki Doi

研究成果: Article査読

84 被引用数 (Scopus)

抄録

Air- and moisture-stable NHC (N-heterocyclic carbene)-derived CNC-type pincer complexes of nickel(II) 4a-d were successfully synthesized, and their structures were fully characterized using X-ray crystallography and analytical and spectroscopic methods. These complexes exhibit a high catalytic activity for the Suzuki-Miyaura coupling reaction of aryl bromides and chlorides with aryl- and alkenylboronic acids, providing an array of biphenyls and stilbenes generally in high yields.

本文言語English
ページ(範囲)389-396
ページ数8
ジャーナルJournal of Organometallic Chemistry
694
3
DOI
出版ステータスPublished - 2009 2 1

ASJC Scopus subject areas

  • Biochemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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