Photochemical behaviors of a tethered 1,3-diketone derivative studied by transient absorption and time-resolved EPR measurements

Atsushi Kobayashi, Minoru Yamaji, Satoru Nakajima, Kimio Akiyama, Shozo Tero-Kubota, Shin Ichiro Kato, Yosuke Nakamura

研究成果: Article査読

4 被引用数 (Scopus)

抄録

Molecular structures of acetyltetralone (AT) in the enol form were investigated based on the photochemical features in comparison with that of benzoylacetone. Laser flash photolysis of AT in fluid media showed the formation of the triplet state which was characterized by time-resolved electron paramagnetic resonance measurements. From these results, the molecular structure of AT in the enol form was concluded to be endocyclic with the C-C double bond in the tetralone moiety.

本文言語English
ページ(範囲)101-105
ページ数5
ジャーナルChemical Physics Letters
555
DOI
出版ステータスPublished - 2013 1 3

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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