Phase relations and extrinsic magnetic properties of Sm–(Fe,Co)–Ti–(Ga)-based alloys for ThMn12-type permanent magnets

A. K. Srinithi, H. Sepehri-Amin, Xin Tang, P. Tozman, J. Li, J. Zhang, S. Kobayashi, T. Ohkubo, T. Nakamura, K. Hono

研究成果: Article査読

4 被引用数 (Scopus)

抄録

Realizing a non-ferromagnetic intergranular phase for the ThMn12-type Sm(Fe,Co,Ti)12 compound is a prerequisite for developing high coercive magnets. In this work, we demonstrate that the addition of Ga into the Sm-(Fe,Co)-Ti system results in the formation of non-ferromagnetic Sm–Ga-rich intergranular phases with good wettability on Sm(Fe,Co,Ti)12 grains. In the Sm-(Fe,Co)-Ti system, when the alloy composition was varied to the Sm-rich region as Sm1+w(Fe0.8Co0.2)11Ti (w = 0–0.7), soft ferromagnetic C15-type Sm(Fe,Co)2 intergranular phase and TbCu7-type Sm(Fe,Co,Ti)~7 phase formed along with the ThMn12-type main phase in the as-cast alloy. We demonstrated that by introducing Ga, the formation of these secondary soft ferromagnetic phases can be hindered as the excess Sm and Ga formed non-ferromagnetic Ba5Si3-type Sm5Ga3 and TII-type SmGa intergranular phases with an excellent wettability on Sm(Fe,Co,Ti)12 grains. Fine Sm(Fe,Co,Ti)12 grains of 1–2 µm, well isolated by the Sm–Ga-rich intergranular phase, were realized by melt-spinning the Ga-doped alloy and the maximum coercivity obtained was 0.5 T. According to the detailed microstructure characterizations, the weak-links to the coercivity of this novel microstructure of well-isolated and fine Sm(Fe,Co,Ti)12-based grains is the presence of defects at the interfaces which could lead to a locally reduced magneto-crystalline anisotropy.

本文言語English
論文番号167866
ジャーナルJournal of Magnetism and Magnetic Materials
529
DOI
出版ステータスPublished - 2021 7月 1

ASJC Scopus subject areas

  • 電子材料、光学材料、および磁性材料
  • 凝縮系物理学

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