Phase-controlled supramolecular photochirogenesis in cyclodextrin nanosponges

Wenting Liang, Cheng Yang, Dayang Zhou, Hitoshi Haneoka, Masaki Nishijima, Gaku Fukuhara, Tadashi Mori, Franca Castiglione, Andrea Mele, Fabrizio Caldera, Francesco Trotta, Yoshihisa Inoue

研究成果: Article

34 引用 (Scopus)


Pyromellitate-bridged cyclodextrin nanosponges (CDNSs) evolved from sol into gel state upon gradual increase of the concentration from 0.2 to 2000 mg mL−1 in water. The enantiodifferentiating geometrical photoisomerizations of (Z)-cyclooctene and (Z, Z)-1,3-cyclooctadiene sensitized by CDNS at various concentrations were critically affected by the phase transition of CDNS to afford the corresponding (E)- and (E, Z)-isomers in the highest enantiomeric excesses in the gel state.

ジャーナルChemical Communications
出版物ステータスPublished - 2013 4 2

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

フィンガープリント Phase-controlled supramolecular photochirogenesis in cyclodextrin nanosponges' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用

    Liang, W., Yang, C., Zhou, D., Haneoka, H., Nishijima, M., Fukuhara, G., Mori, T., Castiglione, F., Mele, A., Caldera, F., Trotta, F., & Inoue, Y. (2013). Phase-controlled supramolecular photochirogenesis in cyclodextrin nanosponges. Chemical Communications, 49(34), 3510-3512.