Phase-controlled supramolecular photochirogenesis in cyclodextrin nanosponges

Wenting Liang, Cheng Yang, Dayang Zhou, Hitoshi Haneoka, Masaki Nishijima, Gaku Fukuhara, Tadashi Mori, Franca Castiglione, Andrea Mele, Fabrizio Caldera, Francesco Trotta, Yoshihisa Inoue

研究成果: Article

34 引用 (Scopus)

抜粋

Pyromellitate-bridged cyclodextrin nanosponges (CDNSs) evolved from sol into gel state upon gradual increase of the concentration from 0.2 to 2000 mg mL−1 in water. The enantiodifferentiating geometrical photoisomerizations of (Z)-cyclooctene and (Z, Z)-1,3-cyclooctadiene sensitized by CDNS at various concentrations were critically affected by the phase transition of CDNS to afford the corresponding (E)- and (E, Z)-isomers in the highest enantiomeric excesses in the gel state.

元の言語English
ページ(範囲)3510-3512
ページ数3
ジャーナルChemical Communications
49
発行部数34
DOI
出版物ステータスPublished - 2013 4 2

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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  • これを引用

    Liang, W., Yang, C., Zhou, D., Haneoka, H., Nishijima, M., Fukuhara, G., Mori, T., Castiglione, F., Mele, A., Caldera, F., Trotta, F., & Inoue, Y. (2013). Phase-controlled supramolecular photochirogenesis in cyclodextrin nanosponges. Chemical Communications, 49(34), 3510-3512. https://doi.org/10.1039/c3cc40542g