Persistent four-coordinate iron-centered radical stabilized by π-donation

Yusuke Sunada, Shintaro Ishida, Fumiya Hirakawa, Yoshihito Shiota, Kazunari Yoshizawa, Shinji Kanegawa, Osamu Sato, Hideo Nagashima, Takeaki Iwamoto

研究成果: Article査読

10 被引用数 (Scopus)

抄録

Dinuclear iron carbonyl complex 2, which contains an elongated unsupported Fe-Fe bond, was synthesized by the reaction between Fe 2 (CO) 9 and phosphinyl radical 1. Thermal Fe-Fe bond homolysis led to the generation of a four-coordinate carbonyl-based iron-centered radical, 3, which is stabilized by π-donation. Complex 3 exhibited high reactivity toward organic radicals to form diamagnetic five-coordinate Fe(ii) complexes.

本文言語English
ページ(範囲)191-198
ページ数8
ジャーナルChemical Science
7
1
DOI
出版ステータスPublished - 2016 1 1

ASJC Scopus subject areas

  • 化学 (全般)

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