Persilastaffanes: Design, synthesis, structure, and conjugation between silicon cages

Takeaki Iwamoto, Daisuke Tsushima, Eunsang Kwon, Shintaro Ishida, Hiroyuki Isobe

研究成果: Article査読

27 被引用数 (Scopus)

抄録

By stepwise catenation of bicyclo[1.1.1]pentasilane units persila[n]staffanes (n=1, 2, and 3) were synthesized as air-stable colorless crystals. A remarkable red-shift of the UV/Vis absorption bands with increasing number of bicyclo[1.1.1]pentasilane units suggests remarkable interactions between bridgehead Si-Si σ orbitals and between cage Si-Si σ orbitals (see picture).

本文言語English
ページ(範囲)2340-2344
ページ数5
ジャーナルAngewandte Chemie - International Edition
51
10
DOI
出版ステータスPublished - 2012 3 5

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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