Periselective and enantioselective carbonyl-ene reaction of isoprene with fluoroalkyl glyoxylate catalysed by modified binaphthol-titanium complex: Asymmetric catalytic synthesis of enantiomerically pure ipsdienol

Masahiro Terada, Koichi Mikami

研究成果: Article査読

35 被引用数 (Scopus)

抄録

The asymmetric reaction of trifluoroethyl glyoxylate 3d with isoprene 4 catalysed by the modified binaphthol-titanium complex 2b provides the ene product 5d in high periselectivity (92%) and complete enantioselectivity, which can be converted to ipsdienol 1, a component of the aggregation pheromone of the bark beetle, genus lps, in enantiomerically pure form.

本文言語English
ページ(範囲)2391-2392
ページ数2
ジャーナルJournal of the Chemical Society, Chemical Communications
23
DOI
出版ステータスPublished - 1995 12 1
外部発表はい

ASJC Scopus subject areas

  • Molecular Medicine

フィンガープリント 「Periselective and enantioselective carbonyl-ene reaction of isoprene with fluoroalkyl glyoxylate catalysed by modified binaphthol-titanium complex: Asymmetric catalytic synthesis of enantiomerically pure ipsdienol」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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