Perfluorinated meso-aryl-substituted expanded porphyrins

Soji Shimizu, Ji Young Shin, Hiroyuki Furuta, Rami Ismael, Atsuhiro Osuka

研究成果: Article査読

72 被引用数 (Scopus)

抄録

Twisted figure-of-eight structures are found for the perfluorinated meso-aryl-substituted expanded porphyrins synthesized from 3,4-difluoropyrrole and pentafluorobenzaldehyde under modified Rothemund-Lindsey conditions. The crystal structure of the [26]hexaphyrin (see picture) consists of two almost planar tripyrrolic subunits which are tilted by approximately 60° in which a distinct alternation in the bond lengths of the π-electronic system is evident.

本文言語English
ページ(範囲)78-82
ページ数5
ジャーナルAngewandte Chemie - International Edition
42
1
DOI
出版ステータスPublished - 2003 1月 3

ASJC Scopus subject areas

  • 触媒
  • 化学 (全般)

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