抄録
Twisted figure-of-eight structures are found for the perfluorinated meso-aryl-substituted expanded porphyrins synthesized from 3,4-difluoropyrrole and pentafluorobenzaldehyde under modified Rothemund-Lindsey conditions. The crystal structure of the [26]hexaphyrin (see picture) consists of two almost planar tripyrrolic subunits which are tilted by approximately 60° in which a distinct alternation in the bond lengths of the π-electronic system is evident.
| 本文言語 | English |
|---|---|
| ページ（範囲） | 78-82 |
| ページ数 | 5 |
| ジャーナル | Angewandte Chemie - International Edition |
| 巻 | 42 |
| 号 | 1 |
| DOI | |
| 出版ステータス | Published - 2003 1月 3 |
ASJC Scopus subject areas
- 触媒
- 化学 (全般)