Paramagnetic-diamagnetic phase transition accompanied by coordination bond formation-dissociation in the dithiolate complex Na[Ni(pdt)2] •2H2O

Shinya Takaishi, Nozomi Ishihara, Kazuya Kubo, Keiichi Katoh, Brian K. Breedlove, Hitoshi Miyasaka, Masahiro Yamashita

研究成果: Article

16 被引用数 (Scopus)

抄録

Bis(2,3-pyrazinedithiolate)nickel complex Na[Ni(pdt)2] •2H2O formed one-dimensional stacks of the Ni(pdt)2 units and showed strong antiferromagnetic interactions along the stacking direction. A first-order phase transition between the paramagnetic and diamagnetic states, which was driven by dimerization of the Ni(pdt)2 units, accompanied by coordination bond formation, was observed.

本文言語English
ページ(範囲)6405-6407
ページ数3
ジャーナルInorganic chemistry
50
14
DOI
出版ステータスPublished - 2011 7 18

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

フィンガープリント 「Paramagnetic-diamagnetic phase transition accompanied by coordination bond formation-dissociation in the dithiolate complex Na[Ni(pdt)<sub>2</sub>] •2H<sub>2</sub>O」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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